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Activated Carbon

Activated carbon is a very mature technology that is designed to help remove taste and odor from water through adsorption of the compounds that cause problems.

There are a variety of different types of carbon that are used industry-wide. They include wood, lignite, coal, and coconut as the most common sources for activated carbon.

Activated carbon operates through adsorption. Adsorption is a surface phenomenon and is therefore directly related to the surface area of the media. In the case of activated carbon, the surface area is related to the pore structure of the raw materials. The cost of the media is also related to the raw materials, so there are other factors that must be taken into consideration besides the total surface area.

Adsorption takes place due to intramolecular attraction between the carbon surface and the substance that is being adsorbed. The force of the attraction can be altered by increasing the density of the carbon or by reducing the distance between the carbon surface and the substance being adsorbed (typically by reducing the median pore size). As the fluid (often water) passes over and through the carbon, the attractive forces between the compounds that are the most attracted to the carbon are adsorbed onto the surface. The compounds that are the most highly attracted are typically organic compounds (which can cause taste, odor and appearance problems), volatile organic compounds (VOCs) and halocarbons such as trihalomethane (THM) compounds and other process wastes.

Once all of the surface area of the carbon has been exhausted through adsorption, the carbon can be regenerated in a number of different manners. The most common is offsite furnace re-activation which involves heating the carbon up to drive off the organic materials that are adsorbed.


BioProcessing

The bioprocessing of biotech products consists of two major processing steps: upstream processing and downstream processing. Upstream processing refers to the culturing of cells and microorganisms to create the bulk bio-product. This processing is typically done through cell culture or fermentation. Downstream processing refers to the separation and refinement of the bulk bio-product into a form suitable for its end use. Typically, this processing includes separation, purification and sterilization.


Distillation

The process of distillation has been known and used for millennia. Although it has primarily been employed as a method of producing alcoholic beverages like whisky and vodka, distillation also works as a technique of water purification. In the 1970s, distillation was a popular method of home water purification, but its use is now largely confined to science laboratories or printing industries.

The Process:
The distillation process utilizes a heat source to vaporize water. The object of distillation is to separate pure water molecules from contaminants with a higher boiling point than water. In the distillation process, water is first heated until it reaches its boiling point and begins to evaporate. The temperature is then kept at a constant. The stable temperature ensures continued water vaporization, but prohibits drinking water contaminants with a higher boiling point from evaporating. Next, the evaporated water is captured and guided through a system of tubes to another container. Finally, removed from the heat source, the steam condenses back into its original liquid form. Contaminants having a higher boiling point than water remain in the original container. This process removes most minerals, most bacteria and viruses, and any chemicals that have a higher boiling point than water from drinking water. For this reason, distillation is sometimes valued as a method of obtaining pure drinking water.

Pros and Cons:
Distillation, similarly to reverse osmosis, provides mineral-free water to be used in science laboratories or for printing purposes, as both functions require mineral-free water. It removes heavy metal materials like lead, arsenic, and mercury from water and hardening agents like calcium and phosphorous. Distillation is often used as the preferred water purification method in developing nations, or areas where the risk of waterborne disease is high, due to its unique capabilities to remove bacteria and viruses from drinking water.

Distillation has several qualities that make it undesirable for the purification of municipally treated water, especially when compared to the decontamination capacities of water filters. Although distillation processes remove mineral and bacterial drinking water contaminants, they do not remove chlorine, chlorine byproducts, or
VOCs. These chemicals, which have a lower boiling point than water, are the major contaminants of municipally treated water. Most dangerous metals and bacteria are removed from water prior to its arrival at a home’s plumbing system. Thus, a distillation system, targeted at the removal of these contaminants, is unnecessary and irrelevant for most people.

Distillation, like reverse osmosis, provides mineral-free water that can be quite dangerous to the body’s system when ingested, due to its acidity. Acidic drinking water strips bones and teeth of valuable and essential mineral constituents.

Furthermore, distillation is an incredibly wasteful process. Typically, 80% of the water is discarded with the contaminants, leaving only one gallon of purified water for every five gallons treated.

Ion Exchange

Ion exchange is a process that includes two very similar applications of the same technology. The first is water softening. This is the process of removing ions from the water and replacing them with sodium ions and chloride ions. The most common use for this is residential, where a homeowner is trying to reduce the hardness or improve the taste of the water that the municipal service provides. This also reduces deposits and scale that can be left from water with a high level of hardness. The second application is deionization. In deionization, the hardness and other ions that are initially in the water are removed and replaced with H+ and OH- ions, which can combine to form water. This is used in applications where extremely pure water is required.

The process works like this: Ion exchange resins (little beads that are charged) are coated with the replacement ions. In the case of water softening the beads are coated with Na+ and Cl-. In the case of deionization, they are coated with H+ and OH-. Water flows over the resin. The ions in the water are attracted to the resin. The ions in the water attach themselves to the resin, and knock off the ions that are already attached.

The resin is exhausted when all of the replacement ions are gone. In order to replenish the resin, also called regenerating the resin, a strong solution of the replenishment ions must be applied to the resin. This removes the ions that came from the water and regenerates the resin. The solution that is used to regenerate the water softeners is concentrated salt water called brine. There are two solutions that are used to regenerate a deionizer. One is a concentrated acid, and the other is a concentrated base.


Media Filtration

There are several concerns in any treatment system that must be considered before final treatment can take place. The two largest and most common concerns are iron in the water and particles that can clog or foul a system. Media filtration, also commonly known as dual-media filtration, can alleviate both of those concerns.

The two media in a media filtration assembly are manganese greensand and anthracite. The manganese greensand acts as a form of chemical treatment that, when in contact with soluble iron in water, reduced the iron from the soluble form to an insoluble form that will precipitate out of solution. The anthracite then can filter both the precipitated iron out of the solution as well as other entrained particles that have entered the water source.

This combination of anthracite and manganese greensand together can remove a majority of particles greater than 10 microns in size. In addition, the filter can be backwashed to remove the entrained particles and iron in order to extend bed life. The manganese will eventually be exhausted and will also need to be regenerated, something which most systems are equipped to do.


Microfiltration

Microfiltration is a form of filtration that has two common forms. One form is crossflow separation. In crossflow separation, a fluid stream runs parallel to a membrane. There is a pressure differential across the membrane. This causes some of the fluid to pass through the membrane, while the remainder continues across the membrane, cleaning it. The other form of filtration is called dead-end filtration or perpendicular filtration. In dead-end filtration, all of the fluid passes through the membrane, and all of the particles that cannot fit through the pores of the membrane are stopped.

Crossflow microfiltration is used in a number of applications, as either a prefiltration step or as a process to separate a fluid from a process stream.

Dead-end microfiltration is used commonly in stopping particles in either prefiltration or final filtration before a fluid is to be used. Cartridge filters are typically composed of microfiltration media.


Nanofiltration

Nanofiltration is a form of filtration that uses membranes to preferentially separate different fluids or ions. Nanofiltration is not as fine a filtration process as reverse osmosis, but it also does not require the same energy to perform the separation. Nanofiltration also uses a membrane that is partially permeable to perform the separation, but the membrane's pores are typically much larger than the membrane pores that are used in reverse osmosis.

Nanofiltration is most commonly used to separate a solution that has a mixture of some desirable components and some that are not desirable. An example of this is the concentration of corn syrup. The nanofiltration membrane will allow the water to pass through the membrane while holding the sugar back, concentrating the solution. As the concentration of the fluid being rejected increases, the driving force required to continue concentrating the fluid increases.

Nanofiltration is capable of concentrating sugars, divalent salts, bacteria, proteins, particles, dyes, and other constituents that have a molecular weight greater than 1000 daltons. Nanofiltration, like reverse osmosis, is affected by the charge of the particles being rejected. Thus, particles with larger charges are more likely to be rejected than others. Nanofiltration is not effective on small molecular weight organics, such as methanol.


Ozonation

Ozone (O3) is one of the strongest oxidizing agents that is readily available. It is used to reduce color, eliminate organic waste, reduce odor and reduce total organic carbon in water.

Ozone is created in a number of different ways, including ultra violet (UV) light, corona discharge of electricity through an oxygen stream (including air), and several others. In treating small quantities of waste, the UV ozonators are the most common, while large-scale systems use either corona discharge or other bulk ozone-producing methods.

Ozone is formed as oxygen (O2) is struck by a source of energy. The bonds that hold the O2 together are broken and three O2 molecules are combined to form two O3 molecules. The ozone begins to break down fairly quickly, and as it does so, it reverts back into O2. The bonds that hold the O atoms together are very weak, which is why ozone acts as a strong oxidant as readily as it does.


What Is Reverse Osmosis?

Reverse osmosis was developed as a water treatment method more than 40 years ago. The process first arose as a technique of desalinating seawater. Once the method’s decontaminating capabilities were recognized, reverse osmosis systems began to be commercially produced for home water purification purposes. Such systems were installed in homes as early as the 1970s. Reverse osmosis systems seemed a viable option to the more costly and energy-wasteful distillation units.

The Process:
The reverse osmosis process depends upon a semi-permeable membrane through which pressurized water is forced. Reverse osmosis, simply stated, is the opposite of the natural osmosis process of water. Osmosis is the name for the tendency of water to migrate from a weaker saline solution to a stronger saline solution, gradually equalizing the saline composition of each solution when a semi-permeable membrane separates the two solutions. In reverse osmosis, water is forced to move from a stronger saline solution to a weaker solution, again through a semi-permeable membrane. Because molecules of salt are physically larger than water molecules, the membrane blocks the passage of salt particles. The end result is desalinated water on one side of the membrane and a highly concentrated, saline solution of water on the other side. In addition to salt particles, this process will remove a select number of drinking water contaminants, depending upon the physical size of the contaminants. For this reason, reverse osmosis has been touted as an effective drinking water purification method.

Pros and Cons:
Reverse osmosis is a valuable water purification process when mineral-free water is the desired end product. Most mineral constituents of water are physically larger than water molecules. Thus, they are trapped by the semi-permeable membrane and removed from drinking water when filtered through a reverse osmosis system. Such minerals include salt, lead, manganese, iron, and calcium. Reverse osmosis will also remove some chemical components of drinking water, including the dangerous municipal additive fluoride.

Although reverse osmosis does extract several contaminants from drinking water, its removal capabilities are not ideally suited to the challenges of the municipally treated water that the overwhelming majority of people receive. Municipal water contains such contaminants as chlorine and volatile organic chemicals (
VOCs). Because these contaminants are physically smaller in size than water, the semi-permeable membrane cannot prohibit them from passing through with the water. Thus, they remain in drinking water.
 


Ultrafiltration

Ultrafiltration is a form of filtration that uses membranes to preferentially separate different fluids or ions. Ultrafiltration is not as fine a filtration process as nanofiltration, but it also does not require the same energy to perform the separation. Ultrafiltration also uses a membrane that is partially permeable to perform the separation, but the membrane's pores are typically much larger than the membrane pores that are used in nanofiltration.

Ultrafiltration is most commonly used to separate a solution that has a mixture of some desirable components and some that are not desirable. One of the uses that demonstrates the usefulness of ultrafiltration is electrodeposition paint recovery. In this instance the paint, composed of a resin, a pigment and water are separated into two streams that can be reused. The first stream includes the water and a small amount of the paint resin, which can be used to rinse the parts later in the process. The paint pigment is separated from that stream and can be reused in the paint bath, allowing the bath to be concentrated to a usable level.

Ultrafiltration is capable of concentrating bacteria, some proteins, some dyes, and constituents that have a larger molecular weight of greater than 10,000 daltons. Ultrafiltration is only somewhat dependent upon the charge of the particle and is much more concerned with the size of the particle. Ultrafiltration is typically not effective at separating organic streams.